Sorry for the delay as our forum is not officially open yet as we are still updating so you may not get many responses for a while. You are doing the right thing getting your bunny to the vet to test bloodwork, adrenals and hormones. Sometimes if a neuter wasn’t 100% successful, leaving behind enough to cause the hormones to still be the bunny’s system, that can be an issue too. Rabbits can also get humpy if the OTHER rabbit has a UTI.
This was actually a problem for one of my bunnies too. We did finally solve the problem and it ended up being a bladder stone that was rubbing in bladder causing a sensation that made Jack want to hump. Not sure if due to stress or just the feeling of needing to urinate all the time for him, or what, but we could not stop him from humping until after he had the stone removed and healed from surgery. He definitely settled down after that. He never showed signs of distress or problem urinating, but how I found out is he had a streak blood in his urine — I put hydrogen peroxide on the urine and it bubbled like crazy (only does that when there is blood). The vet then felt his bladder and found a sizable stone. The blood was from the stone rubbing and cutting his bladder wall with all of humping attempts. You can see his story about this here — https://binkybunny.com/bunnyinfo/jacks-diet/