Firstly, has she been spayed? She will get impulses to spray if she has not been, and so she may be marking on and behind your couch rather than forgetting her toilet habits.
I’ve heard about some rabbits forgetting their litter habits when allowed in bigger areas but I think since she’s been toileting in a very specific area it’s likely she is marking where your smell is very strong.
I think the best thing to do would be use diluted white vinegar or a dedicated solution to break down animal urine to remove her smell from the area (so she is not tempted to continue marking there).
If there is room you could put a litter tray where she is doing this, or block her access and disallow her from the couch. If she is only allowed out when you are around this may work.
After a few weeks of hell with George, we have managed to supervise her out and block her from the bed. Interestingly, after 6 days completely banned from the bed, she had since been up for very short periods of time and hasn’t weed up there again.